Sodium
[[pl:S%F3d]]
Sodium is a chemical element, in the periodic table that has the symbol Na and atom number 11. Sodium is a soft, waxy, silvery reactive element belonging to the alkali metals that is abundant in natural compounds (especially salt water and halite). It is highly reactive, burns with a yellow flame, oxidizes in air and reacts violently with water, forcing it to be kept under oil.
| General | |||||||||||||||||||
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| Name, Symbol, Number | Sodium, Na, 11 | ||||||||||||||||||
| Series | Alkali metal | ||||||||||||||||||
| Group, Period, Block | 1 (I), 3 , s | ||||||||||||||||||
| Density, Hardness | 968 kg/m3, 0.5 | ||||||||||||||||||
| Appearance | silvery white | ||||||||||||||||||
| Atomic | |||||||||||||||||||
| Atomic weight | 22.989770 amu | ||||||||||||||||||
| Atomic radius (calc.) | 180 (190)pm | ||||||||||||||||||
| Covalent radius | 154 pm | ||||||||||||||||||
| van der Waals radius | 227 pm | ||||||||||||||||||
| Electron configuration | [Ne]3s1 | ||||||||||||||||||
| e- 's per energy level | 2, 8, 1 | ||||||||||||||||||
| Oxidation states (Oxide) | 1 (strong base) | ||||||||||||||||||
| Crystal structure | Cubic body centered | ||||||||||||||||||
| Physical | |||||||||||||||||||
| State of matter | solid (nonmagnetic) | ||||||||||||||||||
| Melting point | 370.87 K (207.9 °F) | ||||||||||||||||||
| Boiling point | 1156 K (1621 °F) | ||||||||||||||||||
| Molar volume | 23.78 ×10-3 m3/mol | ||||||||||||||||||
| Heat of vaporization | 96.96 kJ/mol | ||||||||||||||||||
| Heat of fusion | 2.598 kJ/mol | ||||||||||||||||||
| Vapor pressure | 1.43×10-5Pa at 1234 K | ||||||||||||||||||
| Velocity of sound | 3200 m/s at 293.15 K | ||||||||||||||||||
| Miscellaneous | |||||||||||||||||||
| Electronegativity | 0.93 (Pauling scale) | ||||||||||||||||||
| Specific heat capacity | 1230 J/(kg*K) | ||||||||||||||||||
| Electrical conductivity | 21 106/m ohm | ||||||||||||||||||
| Thermal conductivity | 141 W/(m*K) | ||||||||||||||||||
| 1st ionization potential | 495.8 kJ/mol | ||||||||||||||||||
| 2nd ionization potential | 4562 kJ/mol | ||||||||||||||||||
| 3rd ionization potential | 6910.3 kJ/mol | ||||||||||||||||||
| 4th ionization potential | 9543 kJ/mol | ||||||||||||||||||
| 5th ionization potential | 13354 kJ/mol | ||||||||||||||||||
| 6th ionization potential | 16613 kJ/mol | ||||||||||||||||||
| 7th ionization potential | 20117 kJ/mol | ||||||||||||||||||
| 8th ionization potential | 25496 kJ/mol | ||||||||||||||||||
| 9th ionization potential | 28932 kJ/mol | ||||||||||||||||||
| 10th ionization potential | 141362 kJ/mol | ||||||||||||||||||
| Most Stable Isotopes | |||||||||||||||||||
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| SI units & STP are used except where noted. | |||||||||||||||||||
Notable Characteristics
Like the other alkali metals, sodium is a reactive element and is therefore never found unbound in nature. Sodium is a soft, light-weight, silvery white metal that floats in water and decomposes it releasing hydrogen and forming hydroxide. If ground to a fine enough power, sodium will ignite spontaneously in water. However, this metal does not normally ignite in air below 388 Kelvin.
Uses
Sodium in its metallic form is an essential component the making of esters and in the manufacture of organic compounds. This alkali metal is also a component of sodium chloride (NaCl) which it vital to life. Other uses:
- Used in certain alloys to improve their structure.
- In combination with fatty acids, sodium is used in soap.
- Also used to descale (make its surface smooth) metal, and
- to purify molten metals.
NaK, an alloy of sodium and potassium, is an important heat transfer material.
History
Sodium (English, soda) has long been recognized in compounds, but was not isolated until 1807 by Sir Humphry Davy through the electrolysis of caustic soda. In Medieval Europe a compound of sodium with the Medieval Latin name of sodanum was used as a headache remedy. Sodium's symbol, Na, comes for the Latin name for a common sodium compound named Natrium.
Sources
Sodium is relatively abundant in stars and the D spectral lines of this element are among the most prominent in star light. Sodium makes up about 2.6% of the Earth's crust making it the fourth most abundant element overall and the most abundant alkali metal. It is now produced commercially through the electrolysis of completely dry fused sodium chloride. This method is less expensive than the previous method of electrolyzing sodium hydroxide. Metallic sodium cost about 15 to 20 US cents per pound in 1997 but reagent grade (ACS) sodium cost about US$35 per pound in 1990. It is the cheapest of all metals by volume.
Isolation (* follow):
Compounds
Sodium chloride, better known as common salt, is the most common compound of sodium, but sodium occurs in many other minerals, such as amphibole, cryolite, halite, soda niter, zeolite, etc. Sodium compounds are important to the chemical, glass, metal, paper, petroleum, soap, and textile industries. Soap is generally a sodium salt of certain fatty acids.
The sodium compounds that are the most important to industry are common salt (NaCl), soda ash (Na2CO3), baking soda (NaHCO3), caustic soda (NaOH), Chile saltpeter (NaNO3), di- and tri-sodium phosphates, sodium thiosulfate (hypo, Na2S2O3 * 5H2O), and borax (Na2B4O7 * 10H2O).
Isotopes
There are thirteen isotopes of sodium that have been recognized. The only stable isotope is Na-23. Sodium has two radioactive cosmogenic isotopes (Na-22, half-life = 2.605 years; Na-24, half-life = ~ 15 hours).
Precautions
In its powdered form sodium is explosive in water and a poison combined and uncombined with many other elements. This metal should be handled carefully at all times. Sodium can't be maintained in an inert atmosphere and contact with water and other substances that sodium reacts with should be avoided.
Information sources and external links:
WebElements.com - Sodium
EnvironmentalChemistry.com - Sodium