Octane rating
The octane rating is the most important characteristic of gasoline (petrol) and other fuels used in spark-ignition internal combustion engines.
Knock resistance
Engine knocking is the premature detonation of fuel in the compression stroke of the engine. Knocking occurrs when the air-fuel mixture not yet consumed by the flames from the spark plug autoignites all at once (or sometimes perhaps when the flame front goes supersonic because of early ignition timing). A fuel with a high autoignition temperature that burns reasonably fast and thus doesn't need early ignition timing will most often have high practical value knock resistance. Ethyl alcohol is such a fuel.
Octane
Octane is measured relative to a mixture of 2,2,4-trimethylpentane (an isomer of octane) and n-heptane. An 87-octane gasoline has the same knock resistance as a mixture of 87% isooctane and 13% n-heptane. A complementary standard for diesel fuel is the cetane number. A low octane rating means that the fuel has a high tendency to autoignite (bad!)
Measurement methods
The most common type of octane rating worldwide is the Research Octane Number (RON). RON is determined by running the fuel through a specific test engine with a variable compression ratio under controlled conditions, and comparing these results with those for mixtures of isooctane and n-heptane.
There is another type of octane rating, called Motor Octane Number (MON), which is a better measure of how the fuel behaves when under load. MON testing uses a similar test engine to that used in RON testing, but with a preheated fuel mixture, a higher engine speed, and variable ignition timing to further stress the fuel's knock resistance. Depending on the composition of the fuel, the MON of a modern gasoline will be about 8 to 10 points lower than the RON. Normally fuel specifications require both a minimum RON and a minimum MON.
In most countries (including all of Europe and Australia) the "headline" octane that would be shown on the pump is the RON, but in the United States and some other countries the headline number is the average of the RON and the MON, sometimes called the Anti-Knock Index (AKI), Road Octane Number (RdON), Pump Octane Number (PON), or (R+M)/2. Because of the 10 point difference noted above, this means that the octane in the United States will be about 4 to 5 points lower than the same fuel elsewhere: 87 octane fuel, the "normal" gasoline in the US and Canada, would be 91 in Europe.
It is possible for a fuel to have a RON greater than 100, because isooctane is not the most knock-resistant substance available. Racing fuels, straight ethanol, Avgas and liquified petroleum gas (LPG) typically have octane ratings of 110 or significantly higher. Typical "octane booster" additives include tetra-ethyl lead and toluene.
Effects of octane rating
Higher octane ratings correlate to higher activation energies. Activation energy is the amount of energy necessary to start a chemical reaction- since higher octane fuels have higher activation energies, it is less likely that a given compression ratio will cause knocking.
It might seem odd that fuels with higher octane ratings burn less easily, yet are popularly thought of as more powerful. Using a fuel with a higher octane lets an engine be run at a higher compression ratio without having problems with knock. Compression is directly related to power (see engine tuning), so engines that require higher octane usually deliver more power. Some high-performance engines are designed to operate with a compression ratio associated with high octane numbers, and thus demand high-octane gasoline. It should be noted that the power output of an engine also depends on the energy content of its fuel, which bears no simple relationship to the octane rating. A common myth amongst petrol consumers is that adding a higher octane fuel to a vehicle's engine will increase its performance and/or lessen its fuel consumption; this is mostly false—engines perform best when using fuel with the octane rating they were designed for and any increase in performance by using a fuel with a different octane rating is minimal. On the other hand, using the recommended octane for a modern engine makes a huge difference compared to a lower than recommended octane. Here is a white paper that gives an example: http://dinancars.com/whitepapersFile.asp?ID=9 .
The octane rating was developed by the chemist Russell Marker. The selection of n-heptane as the zero point of the scale was due to the availability of very high purity n-heptane, not mixed with other isomers of heptane or octane, distilled from the resin of the Jeffrey Pine. Other sources of heptane produced from crude oil contain a mixture of different isomers with greatly differing ratings, which would not give a precise zero point.
References
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