For clarity, we illustrate the expansion for a single line charge, then
generalize to an arbitrary distribution of line charges. Through this
article,
the primed coordinates such
as
refer to the position of the line charge(s), whereas
the unprimed coordinates such
as refer
to the point at which the potential is being observed. We
use cylindrical coordinates throughout, e.g., an
arbitrary vector
has coordinates
where is the radius from
the axis,
is the azimuthal angle and
is the normal Cartesian coordinate.
By assumption, the line charges are infinitely long and aligned
with the axis.
Cylindrical multipole moments of a line charge
Figure 1: Definitions for cylindrical multipoles; looking down the axis
where
is the shortest distance between the line charge and the observation point.
By symmetry, the electric potential of an infinite line
charge has no -dependence. The line charge
is the charge per unit length in the
-direction, and has units of (charge/length).
If the radius of the observation point is greater than
the radius of the line charge, we may factor out
Conversely, if the radius of the observation point
is less than the radius of the line charge, we may factor out
and expand the logarithms in powers of
which may be written as
where the interior multipole moments are defined
,
,
and
.
General cylindrical multipole moments
The generalization to an arbitrary distribution of line charges
is straightforward. The functional form is the same
and the moments can be written
Note that the
represents the line charge per unit area in the
plane, and has
units of .
Interior cylindrical multipole moments
Similarly, the interior cylindrical multipole expansion has the
functional form
where the moments are defined
Interaction energies of cylindrical multipoles
A simple formula for the interaction energy of cylindrical multipoles
(charge density 1) with a second charge density can be derived. Let be the second charge density, and
define as its integral over z
The electrostatic energy is given by the integral of the charge
multiplied by the potential due to the cylindrical multipoles
If the cylindrical multipoles are exterior, this equation becomes
where , and
are the cylindrical multipole moments of charge distribution 1. This
energy formula can be reduced to a remarkably simple form
where and are the
interior cylindrical multipoles of the second charge density.
The analogous formula holds if charge density 1 is composed of
interior cylindrical multipoles
where and
are the interior cylindrical multipole moments of charge distribution 1,
and and are the
exterior cylindrical multipoles of the second charge density.
As an example, these formulae could be used to determine the interaction
energy of a small protein in the electrostatic field of a
double-stranded DNA molecule; the latter is relatively straight
and bears a constant linear charge density due to the phosphate
groups of its backbone.