Deoxydehydration
Deoxydehydration (DODH) is a chemical reaction for removing two adjacent hydroxyl groups in a vicinal diol to form an alkene.[1] In contrast to hydrodeoxygenation which uses hydrogen as a reductant, deoxydehydration is able to use a variety of other reductants such as alcohols and organic phosphines.[2] In research, the most common homogeneous catalysts for this reaction uses rhenium.
Recently, research has focused on the use of vanadium heterogeneous catalysts for deoxydehydration, such as the conversion of 2,3-butanediol to butene.[3] Although deoxydehydration over vanadium catalysts requires higher temperatures than rhenium catalysts, the reaction appear to proceed without the need for hydrogen or external reductants, which can reduce waste products.[3][4]
 | This article, Deoxydehydration, has recently been created via the Articles for creation process. Please check to see if the reviewer has accidentally left this template after accepting the draft and take appropriate action as necessary.
Reviewer tools: Inform author |
References
- ^ Boucher-Jacobs, Camille; Nicholas, Kenneth M. (2014). "Deoxydehydration of polyols". Topics in Current Chemistry. 353: 163–184. doi:10.1007/128_2014_537. ISSN 0340-1022. PMID 24756633.
- ^ Liu, Shuo; Yi, Jing; Abu-Omar, Mahdi M. (2016). Reaction Pathways and Mechanisms in Thermocatalytic Biomass Conversion II. Green Chemistry and Sustainable Technology. Springer, Singapore. pp. 1–11. doi:10.1007/978-981-287-769-7_1. ISBN 9789812877680.
- ^ a b Kwok, Kelvin Mingyao; Choong, Catherine Kai Shin; Ong, Daniel Sze Wei; Ng, Joy Chun Qi; Gwie, Chuandayani Gunawan; Chen, Luwei; Borgna, Armando (2017-06-07). "Hydrogen-Free Gas-Phase Deoxydehydration of 2,3-Butanediol to Butene on Silica-Supported Vanadium Catalysts". ChemCatChem. 9 (13): 2443–2447. doi:10.1002/cctc.201700301. ISSN 1867-3880.
- ^ Petersen, Allan R.; Nielsen, Lasse B.; Dethlefsen, Johannes R.; Fristrup, Peter (2018-01-08). "Vanadium-Catalyzed Deoxydehydration of Glycerol Without an External Reductant". ChemCatChem. 10 (4): 769–778. doi:10.1002/cctc.201701049. ISSN 1867-3880.
| This article, Deoxydehydration, has recently been created via the Articles for creation process. Please check to see if the reviewer has accidentally left this template after accepting the draft and take appropriate action as necessary.
Reviewer tools: Inform author |